کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5186818 1381114 2008 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Size effect on mechanical properties of micron-sized PS-DVB polymer particles
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Size effect on mechanical properties of micron-sized PS-DVB polymer particles
چکیده انگلیسی

A nanoindentation-based flat punch method has been developed to determine the stress-strain behaviour of single micron-sized Ugelstad polystyrene-co-divinylbenzene (PS-DVB) particles in compression. Five groups of particles with identical chemical compositions but different diameters have been tested. The diameter of the PS-DVB particles varied from 2.6 μm to 25.1 μm. Constant relative deformation rate has been applied with two maximum strain levels of 5% and 10%. Results show that the particle compressive stress-strain behaviour is strongly size-dependent. The smaller the particle size is, the stiffer the particle behaves. Analyses indicate that the pre-load and adhesion during the flat punch test play a minor role on the size effect. The presence of a core-shell structure can possibly be a main contribution to the size effect. Finite element analyses have been carried out to demonstrate this surface shell effect.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 49, Issue 18, 26 August 2008, Pages 3993-3999
نویسندگان
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