کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5187103 | 1381121 | 2006 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Kinetics of styrene minisuspension polymerization using a mixture PVA-SDS as stabilizer
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The kinetics of minisuspension polymerization of styrene at 70 °C using 2-2â²-azobisisobutyronitrile (AIBN) as initiator, polyvinyl alcohol (PVA) and mixture PVA-sodium dodecyl sulfate (SDS) as stabilizers, were studied. The monomer was pre-dispersed by using a high-speed homogenizer apparatus that allowed use mild agitation conditions during the polymerization. It was observed that addition of SDS to a polymerization initially stabilized with PVA highly enhances the colloidal stability of the system. Interfacial tension, viscosity and stability ratio measurements suggest that the PVA and SDS molecules form associations that lead to an electroesteric stabilization mechanism.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 47, Issue 10, 3 May 2006, Pages 3336-3343
Journal: Polymer - Volume 47, Issue 10, 3 May 2006, Pages 3336-3343
نویسندگان
Jorge C. Ramirez, Jorge Herrera-Ordonez, Virgilio A. Gonzalez,