کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5187311 | 1381126 | 2006 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Polymerizations of vinyl-cyclohexane in the presence of C2, C2v, and Cs zirconocene-based catalysts
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Polymerizations of vinyl-cyclohexane (VCH) in the presence of catalytic systems based on zirconocenes belonging to C2, C2v or Cs symmetry group were performed. All polymers were analyzed by 13C NMR spectroscopy and show isotactic microstructure. A steric control mechanism, involving a like 1,3-asymmetric induction of the chiral carbon of the last inserted unit on the chirality of the incoming monomer coordination, is proposed. This would be the only stereocontrol mechanism in the presence of a C2v-symmetry catalyst, and it would enforce or overcome site control in case of active species with C2 and Cs-symmetry, respectively.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 47, Issue 6, 8 March 2006, Pages 1930-1934
Journal: Polymer - Volume 47, Issue 6, 8 March 2006, Pages 1930-1934
نویسندگان
Fabia Grisi, Stefania Pragliola, Chiara Costabile, Pasquale Longo,