کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5187799 | 1381138 | 2009 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis of transparent poly(vinylidene fluoride) (PVdF)/zirconium oxide hybrids without crystallization of PVdF chains Synthesis of transparent poly(vinylidene fluoride) (PVdF)/zirconium oxide hybrids without crystallization of PVdF chains](/preview/png/5187799.png)
Transparent and homogeneous organic-inorganic hybrids with poly(vinylidene fluoride) (PVdF) could be prepared by addition of zirconium oxide nanocrystals (ZrO2-NCs) in a polar aprotic solvent and the subsequent solvent evaporation. The polar aprotic solvents such as DMF, DMAc and DMSO would form hydrogen bonds with Zr-OH groups of the ZrO2-NC and play a role as compatibilizers between the PVdF and ZrO2-NCs. The interpenetration between PVdF and ZrO2-NCs resulted in the nanometer dispersion of PVdF chains in a ZrO2-NC matrix. High dosage of the ZrO2-NCs as physical inhibitors between PVdF polymer chains sufficiently prevented the PVdF chain mobility in the internal of hybrids. The transparency of the PVdF/ZrO2-NC hybrids was dramatically improved by controlling the content of ZrO2-NCs. Novel multifunctional hybrids with high transparency, high refractive index and good mechanical property were obtained by hybridization of PVdF and ZrO2-NCs.
Journal: Polymer - Volume 50, Issue 14, 3 July 2009, Pages 3174-3181