کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5201119 | 1502884 | 2016 | 27 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Degradation behaviour of PLA-based polyesterurethanes under abiotic and biotic environments
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
Study was conducted on the degradation of polyurethanes based on Poly(lactic acid)/Poly(ethylene glycol), containing three differing concentrations of di-isocyanate compound, under three conditions (hydrolytic, thermal and composting). In the hydrolysis study, the effect of temperature and time were studied by techniques including weighting and GPC. Thermal decomposition was examined by thermogravimetry and mass spectroscopy. Composting was performed under standardized conditions and the amount of CO2 was measured. It was found that hydrolysis of the material started almost immediately after exposure to a water environment at both investigated temperatures (37 °C and 55 °C), whereas weight loss exhibited a certain delay. Thermal decomposition of the studied materials started below 230 °C and lactide was identified as the main product. A biodegradation experiment showed that all the investigated samples successfully (>80%) mineralized within 90 days under composting conditions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Degradation and Stability - Volume 129, July 2016, Pages 222-230
Journal: Polymer Degradation and Stability - Volume 129, July 2016, Pages 222-230
نویسندگان
Pavel Kucharczyk, Alena Pavelková, Petr Stloukal, VladimÃr SedlarÃk,