کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5201509 1502896 2015 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Aqueous hydrogen peroxide-induced degradation of polyolefins: A greener process for controlled-rheology polypropylene
ترجمه فارسی عنوان
تجزیه پراکسید هیدروژن آب پلی اتیلن: یک پروسس سبزتر برای پروتئین کنترل رئوولوژی
کلمات کلیدی
پلی پروپیلن، آب اکسیژنه، تقسیم کردن، رئوئولوژی، وزن مولکولی،
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
چکیده انگلیسی
In this work we demonstrate that aqueous hydrogen peroxide is an effective reagent for chain scissioning or vis-breaking of polypropylene during melt-processing to produce a controlled rheology product. The novel process involves the direct injection of aqueous hydrogen peroxide into the polypropylene melt under pressure. The polypropylene produced has reduced molar mass, narrowed molar mass distribution, and is indistinguishable in terms of melt flow rate, molar mass distribution, crystallinity and melt rheology from conventionally vis-broken polypropylene produced using an organic peroxide (2,5-dimethyl-2,5-di-tert-butylperoxyhexane (DHBP)). However, the polypropylene produced in the current process is notably free of the initiator-derived organic volatiles that are formed as by-products in the case where organic peroxides such as DHBP are used.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Degradation and Stability - Volume 117, July 2015, Pages 97-108
نویسندگان
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