کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5201967 | 1502911 | 2014 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Microencapsulation of bisneopentyl glycol dithiopyrophosphate and its flame retardant effect on polyvinyl alcohol
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Microencapsulation of bisneopentyl glycol dithiopyrophosphate and its flame retardant effect on polyvinyl alcohol Microencapsulation of bisneopentyl glycol dithiopyrophosphate and its flame retardant effect on polyvinyl alcohol](/preview/png/5201967.png)
چکیده انگلیسی
Bisneopentyl glycol dithiopyrophosphate (DDPS) has been successfully microencapsulated with melamine formaldehyde (MF) resin as a shell material by in-situ polymerization process in this study. Chemical structures of DDPS and microencapsulated DDPS (MDDPS) were characterized by Fourier-transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS). Morphologies were investigated by scanning electron microscopy (SEM), while particle size and distribution were investigated by granulometry. The results show that microencapsulation can make DDPS particles be coated by MF resin entirely. After microencapsulation, the mean diameter of DDPS increased slightly from 1.405 μm to 2.757 μm, DDPS and MDDPS both were applied in polyvinyl alcohol (PVA) films to compare their flame retardancy. The flame retardation property was evaluated by limiting oxygen index (LOI). Decomposition mechanism was investigated by TG-FTIR, FTIR and SEM. The results indicated that MDDPS has better flame retardancy to PVA, and the LOI of MDDPS/PVA composite is 31.8%. As a fire retardant for PVA, DDPS mainly functions in the gaseous phase rather than in the condensed phase, while MDDPS works in both the gaseous and condensed phase.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Degradation and Stability - Volume 102, April 2014, Pages 81-87
Journal: Polymer Degradation and Stability - Volume 102, April 2014, Pages 81-87
نویسندگان
Wanlu Chen, Xingwei Fu, Weibing Ge, Jianjun Xu, Mengjin Jiang,