کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5202046 | 1381886 | 2013 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and biodegradation of poly(2-pyrrolidone-co-ε-caprolactone)s
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis and biodegradation of poly(2-pyrrolidone-co-ε-caprolactone)s Synthesis and biodegradation of poly(2-pyrrolidone-co-ε-caprolactone)s](/preview/png/5202046.png)
چکیده انگلیسی
Copolyesteramides of 2-pyrrolidone with ε-caprolactone were synthesized by ring-opening copolymerization. The copolymers were random-like and their melting temperature and heat of fusion were dependent on the polymer composition. Biodegradation by a polyamide 4 (PA4) degrading microorganism showed rapid degradation in the region of amide-rich polymer composition. On the contrary, enzymatic hydrolysis using a lipase resulted in a different tendency, that is, ester-rich copolymers hydrolyzed rapidly. Activated sludge makes copolymers degrade to CO2 in wide polymer composition ratio. Copolyesteramides are expected to be applied as an environmentally-friendly plastics or bioabsorbable polymers in medical fields.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Degradation and Stability - Volume 98, Issue 9, September 2013, Pages 1882-1888
Journal: Polymer Degradation and Stability - Volume 98, Issue 9, September 2013, Pages 1882-1888
نویسندگان
Atsuyoshi Nakayama, Naoko Yamano, Norioki Kawasaki, Yasuhide Nakayama,