کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5203383 | 1381929 | 2010 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Highly selective transformation of poly[(R)-3-hydroxybutyric acid] into trans-crotonic acid by catalytic thermal degradation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Highly selective transformation of poly[(R)-3-hydroxybutyric acid] (PHB) into trans-crotonic acid was achieved by thermal degradation using Mg compounds: MgO and Mg(OH)2 as catalysts. Through catalytic action, not only the temperature and Ea value of degradation were lowered by 40-50 °C and 11-14 kJ molâ1, respectively, but also significant changes in the selectivity of pyrolyzates were observed. Notably, Mg(OH)2 showed nearly complete selectivity (â¼100%) to trans-crotonic acid. Kinetic analysis of TG profiles revealed that the catalytic thermal degradation of PHB was initiated by some random degradation reactions, followed by the unzipping β-elimination from crotonate chain-ends as a main process. It was suggested that the Mg catalysts promote the totality of the β-elimination reactions by acting throughout the beginning and main processes, resulting in a lowering in the degradation temperature and the completely selective transformation of PHB.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Degradation and Stability - Volume 95, Issue 8, August 2010, Pages 1375-1381
Journal: Polymer Degradation and Stability - Volume 95, Issue 8, August 2010, Pages 1375-1381
نویسندگان
Hidayah Ariffin, Haruo Nishida, Yoshihito Shirai, Mohd Ali Hassan,