کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5206293 | 1502957 | 2014 | 26 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Reinforcement of EPDM rubber with in situ generated silica particles in the presence of a coupling agent via a sol-gel route
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Reinforcement of EPDM rubber with in situ generated silica particles in the presence of a coupling agent via a sol-gel route Reinforcement of EPDM rubber with in situ generated silica particles in the presence of a coupling agent via a sol-gel route](/preview/png/5206293.png)
چکیده انگلیسی
Ethylene propylene diene monomer rubber (EPDM)-silica (SiO2) composites were prepared by means of an in situ sol-gel process with tetraethoxysilane (TEOS) as precursor and bis-[-3-(triethoxysilyl)-propyl]-tetrasulfide (TESPT) as coupling agent. Homogenous dispersion of the silica particles was observed in all cases, as well as good adhesion between the filler and the matrix. The swelling and gel content results indicated that the number of crosslinks decreased, while the network was still extensive enough to maintain the high gel content. These results indicate that the coupling agent acted as a bridge between the hydrophilic silica and the hydrophobic rubber and enhanced the rubber-silica interactions. This enhanced interaction gave rise to increased thermal stability of the EPDM. The values of the Nielsen model parameters, which gave rise to good agreement with the experimentally determined Young's modulus values, indicate improved dispersion and reduced size of silica aggregates in the EPDM matrix. Good agreement was found between the storage modulus and Young's modulus values. The filler effectiveness (Factor C) indicated a mechanical stiffening effect and a thermal stability contribution by the filler, while the damping reduction (DRNorm) values confirmed that the EPDM interacted strongly with the well dispersed silica particles, and the polymer chain mobility was restricted.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Testing - Volume 33, February 2014, Pages 97-106
Journal: Polymer Testing - Volume 33, February 2014, Pages 97-106
نویسندگان
T.H. Mokhothu, A.S. Luyt, M. Messori,