کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5209394 | 1503051 | 2017 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A crosslinked bis(amino)-containing polymer as a remarkable support for heterogeneous palladium-catalyzed Suzuki-Miyaura reaction
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: A crosslinked bis(amino)-containing polymer as a remarkable support for heterogeneous palladium-catalyzed Suzuki-Miyaura reaction A crosslinked bis(amino)-containing polymer as a remarkable support for heterogeneous palladium-catalyzed Suzuki-Miyaura reaction](/preview/png/5209394.png)
چکیده انگلیسی
Through the substitution reaction of hexachlorocyclotriphosphazene (HCCP) and 4,4â²-diaminobiphenyl (DABP), a crosslinked polymer HCCP-DABP was synthesized by a conventional and convenient route. Owing to the strong coordination ability of pincer-type bis(amino) scaffold in the matrix, the polymer was successfully used as a support to form stable palladium catalyst complex Pd/HCCP-DABP. The palladium catalyst showed excellent reactivity in Suzuki-Miyaura cross-coupling reaction. In addition, the catalyst can be readily recovered and reused for further transformations at least 10 times without significant decrease in catalytic activity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Reactive and Functional Polymers - Volume 110, January 2017, Pages 38-46
Journal: Reactive and Functional Polymers - Volume 110, January 2017, Pages 38-46
نویسندگان
Yiming Wang, Cuifen Lu, Guichun Yang, Zuxing Chen, Junqi Nie,