کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5209826 | 1503073 | 2015 | 20 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Separation of butyric acid in fixed bed column with solvent impregnated resin containing ammonium ionic liquid
ترجمه فارسی عنوان
جداسازی اسید بوتیریک در ستون ثابت با رزین آغشته کننده حلال حاوی مایع یونی آمونیوم
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کلمات کلیدی
استخراج، اسید بوتیریک، رزین آغشته کننده حلال، ستون تخت ثابت مایع یونی آمونیوم،
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
چکیده انگلیسی
Batch equilibrium and fixed bed column extraction experiments for the extraction of butyric acid (BA) into solvent impregnated resin (SIR) have been done. Microporous Amberlite XAD-1180N was impregnated with an ammonium ionic liquid (IL) trialkylmethylammonium bis(2,4,4-trimethylpentyl)phosphinate. The BA extraction capacity isotherm has not a Langmuir type shape and no finite capacity was observed. The loading of the impregnated IL with the extracted BA at 37 °C is in agreement with the loading from L/L extraction equilibrium of BA at 25 °C. Capacity of freshly prepared SIR particles is superior to classical porous ion-exchangers. Both the temperature and the superficial velocity in column influence the shape of the breakthrough-curve in fixed bed extraction of BA using SIR. Sharpening of the breakthrough curve was observed with the increasing temperature and decreasing superficial velocity. Stripping with water is not efficient for the regeneration of the loaded column after extraction because of low concentration of the product acid in the obtained effluent. Higher BA concentration was achieved by stripping with 0.15 kmol mâ3 and 0.075 kmol mâ3 NaOH solutions. The combination of initial water stripping coupled with consecutive stripping by alkali can be beneficial for decreasing the consumption of chemicals and further processing of the product. After two extraction/stripping cycles, a stable capacity was achieved and sustained for 14 cycles, showing the possibility of long-term application of the prepared SIR in real technology.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Reactive and Functional Polymers - Volume 87, February 2015, Pages 29-36
Journal: Reactive and Functional Polymers - Volume 87, February 2015, Pages 29-36
نویسندگان
Marek BlahuÅ¡iak, Å tefan Schlosser, Július Annus,