کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5209860 | 1503080 | 2014 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Cyclic polymers as a building block for cyclic brush polymers and gels
ترجمه فارسی عنوان
پلیمرهای سیکلی به عنوان یک بلوک ساختمانی برای پلیمرها و ژل های مسطح کننده سیکل
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کلمات کلیدی
پلیمر سیسیلیک پلیمر برس ژل پلیمری پلیمریزاسیون متادهای حلقه، شیمی کلیک کنید
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
چکیده انگلیسی
Cyclic polymers, as one of the oldest topological polymers, are undergoing resurgence. This is largely ascribed to the significant achievements in modern polymer chemistry. The novel ring-expansion techniques have conveniently produced varied cyclic polymers with highly topological purity and on large scales, which should facilitate their use in the near future. Beyond the monocyclic molecular conformations, the combination of controlled polymerization techniques and click chemistry have established a robust strategy for preparing cyclic polymers with more complex architectures, such as theta, eight, and tadpole shapes. This diversification in cyclic polymer composition and conformation significantly broadens interest in the cyclic polymers. However, compared to the synthesis achievements, the exploration of cyclic polymer property and application are lagging behind. Recently, we explored the ring-expansion metathesis polymerization on various functional ring-strained olefin monomers to produce cyclic functional polymers, which were then used as the building blocks to fabricate cyclic brush polymers and cyclic gel materials and will be discussed here.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Reactive and Functional Polymers - Volume 80, July 2014, Pages 40-47
Journal: Reactive and Functional Polymers - Volume 80, July 2014, Pages 40-47
نویسندگان
Ke Zhang, Gregory N. Tew,