کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5210524 | 1382898 | 2011 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Sulfonic acid functionalized poly (ethylene glycol dimethacrylate-1-vinyl-1,2,4-triazole) as an efficient catalyst for the synthesis of methyl propionate
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
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چکیده انگلیسی
Sulfonic acid functionalized poly (ethylene glycol dimethacrylate-1-vinyl-1,2,4-triazole), poly (EGDMA-VTAZ-SO3H) (average diameter 1.0-1.5Â mm), was found to be efficient solid acid catalyst for the esterification of methanol and propionic acid under heterogeneous reaction conditions. The pristine polymer, poly (EGDMA-VTAZ), was produced by suspension polymerization and then proton-conducting polymer was obtained by blending of poly (EGDMA-VTAZ) with different percentage of H2SO4 solutions. The protonation of aromatic heterocyclic rings was proved with Fourier-transform infrared spectroscopy (FT-IR). Thermo gravimetric (TG) analysis showed that the catalyst is thermally stable up to 573Â K. The surface morphology of the catalyst was characterized by scanning electron microscopy (SEM). Poly (EGDMA-VTAZ-SO3H) beads can be regenerated and reused, so this provides a potential application. It has a rate constant which exceeds that of Amberlyst-15 by a factor of about four at 333Â K. As for the reaction equilibrium constant (Ke), which is independent of temperature ranging from 318 to 343Â K, was determined to be 3.16. The apparent activation energy was found to be 41.6Â kJÂ molâ1 for poly (EGDMA-VTAZ-SO3H).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Reactive and Functional Polymers - Volume 71, Issue 2, February 2011, Pages 219-224
Journal: Reactive and Functional Polymers - Volume 71, Issue 2, February 2011, Pages 219-224
نویسندگان
Beyhan Erdem, Ali Kara,