کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5210863 1382922 2010 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Syntheses and self-assembly of novel polyurethane-itaconic acid copolymer hydrogels
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Syntheses and self-assembly of novel polyurethane-itaconic acid copolymer hydrogels
چکیده انگلیسی

Novel physically crosslinked polyurethane-itaconic acid (PU-I) copolymer hydrogels were synthesized by the macroiniferter-controlled radical polymerization method. The structures of the PU-I copolymer hydrogels were characterized by 1H NMR, FTIR, GPC, and DSC. The water contact angles and self-assembly of the PU-I copolymer hydrogels have been investigated. The results revealed that PU-I copolymer hydrogels have good hydrophilicity, so the water contact angles of polyurethane could be easily adjusted by controlling the content of the hydrophilic vinyl monomers. The PU-I copolymer hydrogels were subjected to solvent-induced self-assembly in THF + water to construct a variety of morphologies. The morphology of the PU-I copolymer hydrogels' self-assembly was observed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM), and the mechanism of self-assembly was investigated.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Reactive and Functional Polymers - Volume 70, Issue 3, March 2010, Pages 175-181
نویسندگان
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