کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5210969 | 1382930 | 2009 | 5 صفحه PDF | دانلود رایگان |

Dendron-like branched polystyrenes are prepared using atom transfer radical polymerization (ATRP) and chain-end functionalization. The growing chain ends of polystyrene from ATRP are end-capped with 1,4-benzoquinone to incorporate branching points and ATRP initiating groups to the chain ends. Sequential ATRP of styrene initiated from the chain ends builds up the polystyrene arms. The number-averaged molecular weights of the first, second, and third generations of dendron-like polystyrene polymers calculated from their respective 1H NMR spectra are 5960, 6850, and 9150Â g/mol, respectively. The NMR-data are consistent with the molecular weights determined by GPC. An approach to prepare dendron-like polymers through ATRP and chain-end functionalization is developed.
Journal: Reactive and Functional Polymers - Volume 69, Issue 7, July 2009, Pages 424-428