کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5211090 1382935 2009 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis of 4,4′-bipyridinium salts of poly(2-methoxyaniline-5-sulfonic acid) and their self-doping and chemical properties
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Synthesis of 4,4′-bipyridinium salts of poly(2-methoxyaniline-5-sulfonic acid) and their self-doping and chemical properties
چکیده انگلیسی
4,4′-Bipyridinium salts (PAS-BPy(R)s) of poly(2-methoxyaniline-5-sulfonic acid) (PAS) were synthesized by the reaction of PAS with N-4-halophenyl-4-(4-pyridyl)pyridinium chlorides (BPy(X)s) or N-2,4-dinitrophenyl-4-(4-pyridyl)pyridinium chloride (BPy(NO2)). The UV-vis, ESR and X-ray photoelectron spectroscopy (XPS) data suggested the occurrence of the self-doping in PAS-BPy(R)s that was based on the electron transfer from the nitrogen atom in the polymer backbone to the 4,4′-bipyridinium unit. PAS-BPy(R)s behaved as polymeric electrolytes in the dilute solutions. Electric conductivity of PAS-BPy(R)s was almost constant when it was measured in the range of 1 ⩽ pH ⩽ 10. Cyclic voltammetry suggested that PAS-BPy(R)s received two-step electrochemical reduction in film, and the electrochemical reaction was accompanied with electrochromism.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Reactive and Functional Polymers - Volume 69, Issue 2, February 2009, Pages 91-96
نویسندگان
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