کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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5211459 | 1382952 | 2007 | 11 صفحه PDF | دانلود رایگان |

Synthesis of polyaniline (PANi) nanodispersions with and without the presence of a reactive dye has been performed via micellar chemical oxidative polymerisation using dodecylbenzene sulfonic acid (DBSA) as the dispersant. The dye used was a textile reactive dye (Carbolan Blue - CB) which was chosen due to it's structural similarity to DBSA. The polymers formed were PANi · DBSA and PANi · DBSA · CB. The inclusion of the CB dye appeared to facilitate the polymerisation process as observed from open circuit potential measurements during polymerisation. Using transmission electron microscopy, PANi · DBSA · CB was shown to have an average particle size larger than that observed for PANi · DBSA. The CB dye was shown to be incorporated into the polymer by Raman spectroscopy. The CB containing polymer was amenable to protonation/deprotonation as well as redox switching.
Journal: Reactive and Functional Polymers - Volume 67, Issue 3, March 2007, Pages 173-183