Palladium-catalyzed borylation of m-dibromobenzene derivative and its applications in one-pot tandem Suzuki-Miyaura arenes synthesis

One-step synthesis of monomer, dimmer, trimer, and tetramer boronates through Miyaura reaction in a moderate yields has been reported. Furthermore, the boronates can be followed by Suzuki-Miyaura cross-coupling without purification.