کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5216415 | 1383263 | 2014 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis and photovoltaic properties of new [1,2,5]thiadiazolo[3,4-c]pyridine-based organic Broadly absorbing sensitizers for dye-sensitized solar cells Synthesis and photovoltaic properties of new [1,2,5]thiadiazolo[3,4-c]pyridine-based organic Broadly absorbing sensitizers for dye-sensitized solar cells](/preview/png/5216415.png)
In this paper, by introducing [1,2,5]thiadiazolo[3,4-c]pyridine (PT) as an auxiliary acceptor into the molecular design of organic sensitizers, we have synthesized four new dyes (PT1-PT4) for dye-sensitized solar cells (DSSCs) with triphenylamine or N,N-diphenylthiophen-2-amine as the donor units and thiophene or benzene as the Ï-bridges, respectively. All the structures, optical and electrochemical properties were fully characterized. Nanocrystalline TiO2 dye-sensitized solar cells were also fabricated using these dyes. Among them, PT2-based DSSCs showed the highest overall conversion efficiency of 6.11% with Voc=668Â mV, Jsc=12.61Â mAÂ cmâ2 and a fill factor (FF)=0.74 after a chenodeoxycholic acid (CDCA) treatment under standard illumination condition (100Â mWÂ cmâ2 simulated AM 1.5 solar light).
Journal: Tetrahedron - Volume 70, Issue 25, 24 June 2014, Pages 3901-3908