کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5218901 1383341 2013 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrochemical oxidation of aminophenols in the presence of benzenesulfinate
ترجمه فارسی عنوان
اکسیداسیون الکتروشیمیایی آمینوفنول ها در حضور بنزن سولفانات
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
چکیده انگلیسی

The anodic oxidation of aminophenols and their amino-protected derivatives was investigated by using cyclic voltammetry and preparative electrolysis methods. The results showed that like the catechols the amino-protected aminophenol could also undergo Michael addition, and that the benzenesulfonate group was regioselectively introduced at the meta-position of the amino group. In contrast, the expected products were not formed from the oxidation of unprotected aminophenols. Finally, a reaction mechanism is proposed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 69, Issue 2, 14 January 2013, Pages 658-663
نویسندگان
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