کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5218959 | 1383342 | 2012 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermochemiluminescence as a fast method to detect and characterize hydroperoxide moieties in novel 3-hydroperoxyisothiazole 1,1-dioxides
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
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چکیده انگلیسی
Hydroperoxy compounds are important for selective oxidation of organic precursors in the chemical industry. Moreover, novel 3-hydroperoxyisothiazole 1,1-dioxides (N-phthalimidyl sultams) have been shown to be potent and specific inhibitors of acetylcholinesterase (AChE) an important enzyme in the neurotransmitter process. The inhibitory potential of these novel compounds is clearly linked to the hydroperoxide moiety. Hydroperoxides are known for their chemi- and thermochemiluminescent reactivity. In this study we tested thermochemiluminescence (TCL) as a fast method to detect and characterize the hydroperoxide moiety in structurally different synthetic organic hydroperoxides.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 68, Issue 33, 19 August 2012, Pages 6765-6771
Journal: Tetrahedron - Volume 68, Issue 33, 19 August 2012, Pages 6765-6771
نویسندگان
Matthias Gilbert, Valeria Zakharova, Anna Ramenda, Christian Jebsen, Bärbel Schulze, Christian Wilhelm,