کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
52197 46866 2011 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
One-pot synthesis of cresols from toluene and hydroxylamine catalyzed by ammonium molybdate
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
One-pot synthesis of cresols from toluene and hydroxylamine catalyzed by ammonium molybdate
چکیده انگلیسی

One-pot synthesis of cresols from toluene and hydroxylamine catalyzed by ammonium molybdate was investigated under mild conditions. The hydroxylation reaction was strongly dependent on reaction medium, temperature, the amount of catalyst and hydroxylamine. Moreover, the reaction took place more efficiently in a closed system than in open air. High toluene conversion (72.9%) and cresol selectivity (79.4%) were obtained at 80 °C in water–acetic acid–sulfuric acid medium.

Figure optionsDownload as PowerPoint slideResearch highlights
► One-pot synthesis of cresols from toluene and hydroxylamine was investigated.
► Ammonium molybdate was used as a catalyst.
► The catalyst exhibited high activity in H2O–HOAc–H2SO4 medium.
► High toluene conversion (72.9%) and cresol selectivity (79.4%) were obtained at 80 °C.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 12, Issue 12, 1 July 2011, Pages 1109–1112
نویسندگان
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