کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5221509 1383422 2012 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Cyanuric chloride catalyzed Beckmann rearrangement of ketoximes in biodegradable ionic liquids
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Cyanuric chloride catalyzed Beckmann rearrangement of ketoximes in biodegradable ionic liquids
چکیده انگلیسی

Imidazolium-based ionic liquids (ILs) containing ester moieties in the side chain were successfully used as an alternative to traditional ILs in the Beckmann rearrangement of ketoximes catalyzed by 2,4,6-trichloro[1,3,5]triazine. The procedure is mild and suitable for both aromatic and cycloaliphatic substrates affording the rearrangement products in good to quantitative yields. The process is eco-sustainable since these ILs are biodegradable and in addition they can be recovered and reused.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 68, Issue 7, 18 February 2012, Pages 1947-1950
نویسندگان
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