کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5223460 | 1383487 | 2010 | 6 صفحه PDF | دانلود رایگان |
A novel β-cyclodextrin (β-CD) derivative containing mono-phenylamino (MPA-β-CD) was newly synthesized by classical Mitsunobu reaction in good yield, and its structure has been confirmed by 1H NMR, 13C NMR and electrospray ionization mass spectra. The compound MPA-β-CD was immobilized onto glassy carbon electrode (GCE) by diazotization, and with this modified electrode the binding behavior of MPA-β-CD for ferrocene (Fc) was investigated qualitatively, and the comparison of differential pulse voltammetry before and after immersion in ferrocene solution indicated that the MPA-β-CD immobilized GCE exhibited the molecular recognition behavior between β-CD and ferrocene.
A novel β-cyclodextrin derivative containing mono-phenylamino group was obtained by Mitsunobu reaction. The molecular recognition behavior of this new compound was investigated by modifying it on glassy carbon electrode by diazotization.
Journal: Tetrahedron - Volume 66, Issue 39, 25 September 2010, Pages 7815-7820