کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5226055 | 1383565 | 2009 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
2-Aminophenyl diphenylphosphinite as a new ligand for heterogeneous palladium-catalyzed Heck-Mizoroki reactions in water in the absence of any organic co-solvent
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
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چکیده انگلیسی
In this article, 2-aminophenyl diphenylphosphinite has been introduced as a new ligand for the Heck-Mizoroki reactions of aryl halides with styrene and n-butylacrylate in water in the presence of palladium acetate. This ligand is easily prepared from the reaction of chlorodiphenyl phosphine with 2-aminophenol in high yield. Pre-catalyst [Pd(OAc)2] in the presence of the ligand produces a black solid mass. The solid catalyst has been recycled for the reaction of bromobenzene with styrene for six runs without appreciable loss of its catalytic activity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 65, Issue 34, 22 August 2009, Pages 7079-7084
Journal: Tetrahedron - Volume 65, Issue 34, 22 August 2009, Pages 7079-7084
نویسندگان
Habib Firouzabadi, Nasser Iranpoor, Mohammad Gholinejad,