کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5227964 | 1383620 | 2005 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Polystyrene-supported triphenylarsines: useful ligands in palladium-catalyzed aryl halide homocoupling reactions and a catalyst for alkene epoxidation using hydrogen peroxide Polystyrene-supported triphenylarsines: useful ligands in palladium-catalyzed aryl halide homocoupling reactions and a catalyst for alkene epoxidation using hydrogen peroxide](/preview/png/5227964.png)
The utility of both soluble (non-cross-linked) and insoluble (cross-linked) polystyrene-supported triphenylarsine reagents were examined. These reagents were prepared by standard radical polymerization methodology and used in palladium-catalyzed homocoupling reactions of aryl halides. The insoluble reagent was also used as a catalyst precursor in heterogeneous alkene epoxidation reactions in which aqueous hydrogen peroxide was the stoichiometric oxidant. For the aryl halide homocoupling reactions, both reagents worked well and afforded similar results. Unhindered aryl iodides afforded the best yields in the shortest reaction times compared to aryl bromides. The epoxidation reactions of unfunctionalized alkenes were not very efficient. This was probably due to the hydrophobicity of the polystyrene matrix, which did not swell in the reaction medium. Thus, since a microporous, gel-type polystyrene matrix was used, the majority of the arsine groups were inaccessible to the reaction components and therefore incapable of participating in catalysis.
Graphical Abstract
Journal: Tetrahedron - Volume 61, Issue 51, 19 December 2005, Pages 12053-12057