کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5267269 1385334 2012 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Metal-free oxidative amide formation with N-hydroxysuccinimide and hypervalent iodine reagents
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Metal-free oxidative amide formation with N-hydroxysuccinimide and hypervalent iodine reagents
چکیده انگلیسی
An oxidative amide formation using N-hydroxysuccinimide and hypervalent iodine reagents was developed. The method enables a wide range of aldehydes and amines to be coupled under mild reaction conditions providing amide in good to excellent yield. The radical species in the reaction mixture was observed for the first time using ESR measurement, and along with other mechanistic investigations, a plausible mechanism of the reaction was proposed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron Letters - Volume 53, Issue 38, 19 September 2012, Pages 5094-5098
نویسندگان
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