کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5269774 1385398 2014 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Recent advances in asymmetric fluorination and fluoroalkylation reactions via organocatalysis
ترجمه فارسی عنوان
پیشرفت های اخیر در واکنش های فلوراسیون نامتقارن و واکنش های فلوراولاسیون از طریق کاتالیزوری
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
چکیده انگلیسی

The past decade has witnessed the significant advances of asymmetric organocatalytic fluorination, monofluoroalkylation, gem-difluoroalkylation, and trifluoromethylation. This digest summarizes the latest progress of these reactions. In the research area of asymmetric organocatalytic fluorination, a new catalysis concept, chiral anion phase-transfer catalysis strategy, has emerged and has proved to be highly efficient. Asymmetric organocatalytic monofluoroalkylation and gem-difluoroalkylation have been much less explored and the Lewis base/acid catalysis has been the most used strategy. Compared with electrophilic trifluoromethylation, nucleophilic trifluoromethylation has been intensively studied in the research field of asymmetric organocatalytic trifluoromethylation.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron Letters - Volume 55, Issue 45, 5 November 2014, Pages 6147-6155
نویسندگان
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