کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5270209 | 1385410 | 2014 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Palladium(II) chalcogenolate complexes as catalysts for CC cross-coupling and carbonylative Suzuki coupling reactions
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The catalytic activity of palladium chalcogenolate complexes, [PdCl(ECH2CH2NMe2)]3 (EÂ =Â S or Se), [PdCl(ECH2CH2CH2NMe2)]2 and [PdCl(SeCH2CH2NMe2)(PPh3)] has been investigated in carbonylative Suzuki coupling reactions. The phosphine complex has also been used as a catalyst in CC cross coupling reactions involving an aryl halide and either triaryl bismuth or aryl boronic acid (Suzuki coupling). The catalytic system was also explored for other carbonylation reactions including carbonylative Sonogashira coupling and amino carbonylation reaction. The phosphine complex showed better activity in carbonylative Suzuki coupling reactions than dimeric and trimeric complexes. All the complexes showed comparable activity in Suzuki coupling reactions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron Letters - Volume 55, Issue 18, 30 April 2014, Pages 2953-2956
Journal: Tetrahedron Letters - Volume 55, Issue 18, 30 April 2014, Pages 2953-2956
نویسندگان
Dilip K. Paluru, Sandip Dey, Kamal R. Chaudhari, Mayur V. Khedkar, Bhalachandra M. Bhanage, Vimal K. Jain,