کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5364956 | 1388323 | 2008 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Understanding barium sulfate precipitation onto stainless steel
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کلمات کلیدی
68.55.Jk82.80.Fk82.45.Bb61.10.Nz81.10.Dn61.72.Ss - 61.72.SS68.08.−p - 68.08.-p68.37.−d - 68.37.-d84.37.+q - 84.37 + qPrecipitation - بارندگیInterfaces - رابط هاBarium sulfate - سولفات باریمElectrochemical impedance spectroscopy - طیف سنجی امپدانس الکتروشیمیاییScale - مقیاسInhibitors - مهارکنندهMorphology - مورفولوژی(ریخت شناسی)X-ray diffraction - پراش اشعه ایکس
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
This paper investigates the influence of barium sulfate scaling and scaling inhibitors on the electrochemical behaviour of stainless steel. The results of a synchrotron radiation grazing incidence X-ray diffraction (SR-GIXRD) and electrochemical impedance spectroscopy (EIS) study on stainless steel shows that different scaling inhibitors interact uniquely with the substrate when barium sulfate is precipitated on the electrode surface. The main effect of the substrate in the presence of inhibitor is a tendency to form smaller barium sulfate particles. The SR-GIXRD patterns obtained in the presence of the two inhibitors were different to each other and to the control, with the carboxylate showing greater amounts of barite solids precipitated together with iron(III) and (II) sulfate, while the phosphonate showed low amounts of barite solid were precipitated. The presence of iron sulfates on the electrode surface as detected by SR-GIXRD, in the case of NTA, suggests that scaling inhibitors are not always benign, and can promote the dissolution of iron species from the substrate.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 254, Issue 11, 30 March 2008, Pages 3459-3468
Journal: Applied Surface Science - Volume 254, Issue 11, 30 March 2008, Pages 3459-3468
نویسندگان
Franca Jones, Phillip Jones, Roland De Marco, Bobby Pejcic, Andrew L. Rohl,