کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5372914 | 1504189 | 2016 | 10 صفحه PDF | دانلود رایگان |
- Proton transfer and tautomerism are revisited from quantum viewpoint.
- Neutron-diffraction gives evidence for long-range correlations for protons.
- We introduce a decoherence-free macroscopic-scale crystal-state.
- All observations accord with the principle of complementarity.
- Computational-chemistry models are inappropriate.
Measurements via different techniques of the crystal of benzoic acid have led to conflicting conceptions of tautomerism: statistical disorder for diffraction; semiclassical jumps for relaxometry; quantum states for vibrational spectroscopy. We argue that these conflicts follow from the prejudice that nuclear positions and eigenstates are pre-existing to measurements, what is at variance with the principle of complementarity. We propose a self-contained quantum theory. First of all, new single-crystal neutron-diffraction data accord with long-range correlation for proton-site occupancies. Then we introduce a macroscopic-scale quantum-state emerging from phonon condensation, for which nuclear positions and eigenstates are indefinite. As to quantum-measurements, an incoming wave (neutron or photon) entangled with the condensate realizes a transitory state, either in the space of static nuclear-coordinates (diffraction), or in that of the symmetry coordinates (spectroscopy and relaxometry). We derive temperature-laws for proton-site occupancies and for the relaxation rate, which compare favorably with measurements.
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Journal: Chemical Physics - Volume 479, 10 November 2016, Pages 26-35