کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
539349 1450355 2014 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Double phase tinoxide/tin/MWCNT nanocomposite negative electrodes for lithium microbatteries
موضوعات مرتبط
مهندسی و علوم پایه مهندسی کامپیوتر سخت افزارها و معماری
پیش نمایش صفحه اول مقاله
Double phase tinoxide/tin/MWCNT nanocomposite negative electrodes for lithium microbatteries
چکیده انگلیسی


• Double phase Sn/SnO2/MWCNT composite electrode was produced for Li microbatteries.
• Electrode was produced as flexible, free-standing and light-weight.
• Sn/SnO2 was deposited on the MWCNT surfaces revealing a core–shell structure.
• Sn/SnO2/MWCNT electrodes prevented a capacity of 610 mAh g−1 even at 100 cycles.

As anode material for lithium microbatteries, SnO2/Sn/MWCNT nanocomposites were produced by two steps; thermal evaporation and subsequent plasma oxidation. Metallic tin was first evaporated onto free-standing MWCNT buckypapers having controlled porosity and subsequent RF plasma oxidized in Ar:O2(1:1) gas mixture. The ratio between metallic tin (Sn) and tinoxide (SnO2) was controlled with plasma oxidation time. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to determine the structure and morphology of the obtained nanocomposites. The discharge/charge tests, electrochemical impedance spectroscopy (EIS) and rate capability tests were carried out to characterize the electrochemical properties of the composite. The flexible and free-standing SnO2/Sn/MWCNT nanocomposite electrode showed core–shell and functionally gradient composite structure. SnO2/Sn electrode was failed after 30 cycles and MWCNT paper electrode displays only 75 mAh g−1 capacity value between 10 and 100 cycles. SnO2/Sn/MWCNT double phase electrode, exhibited 610 mAh g−1 specific discharge capacity even after 100 cycles.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microelectronic Engineering - Volume 126, 25 August 2014, Pages 143–147
نویسندگان
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