کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5395230 1505659 2011 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Predicting organic thin-film transistor carrier type from single molecule calculations
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Predicting organic thin-film transistor carrier type from single molecule calculations
چکیده انگلیسی
The hole- or electron-conducting ability of functionalized acene-derivative organic molecular semiconductor thin-films can be predicted by electrochemical measurements of the frontier molecular orbital energies. We find that PM6 calculations using a Conductor-like Polarizable Continuum Model (CPCM) solvent are in complete qualitative agreement with the electrochemical results, and B3LYP/6-311+G(d,p)//B3LYP/6-31G(d) CPCM calculations are in quantitative agreement with the electrochemical results, given a suitable linear scaling function presented in this paper. These calculated electrochemical results can thus be used to predict the charge-carrier type of the resulting thin-film organic semiconductor device, enabling rapid computational screening of new materials. We also examine the role of internal reorganization energy and dielectric medium shifts to modify carrier conduction. Neither effect is large enough to explain the experimental results, demonstrating the importance of the relative orientations and packing of the molecules in the thin-film.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Computational and Theoretical Chemistry - Volume 966, Issues 1–3, June 2011, Pages 70-74
نویسندگان
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