کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5395477 1505719 2016 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
An X-ray photoelectron spectroscopy and quantum chemical study of copper(II) β-diketonates and Cu(HFA)2 complexes with imidazoline ligands
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
An X-ray photoelectron spectroscopy and quantum chemical study of copper(II) β-diketonates and Cu(HFA)2 complexes with imidazoline ligands
چکیده انگلیسی
An X-ray photoelectron spectroscopy study of the charge and spin state of copper(II) β-diketonates and Cu(hfa)2 (hfa-hexafluoroacetylacetonate) complexes with imidazoline ligands is performed with comparison to the data of quantum chemical calculations. It is shown that the structure of the spectra of copper is described by a superposition of the |2p53d9> and | 2p53d10L> electronic states determined by electron transfer processes between copper and L ligand atoms. It is found that during the coordination of imidazoline ligands to the Cu(hfa)2 complex the spin density is redistributed through the chain of chemical bonds from the ligand nitroxyl group to the copper atom.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electron Spectroscopy and Related Phenomena - Volume 212, October 2016, Pages 11-20
نویسندگان
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