کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5395927 1505738 2014 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Titanium-induced charge of Si(0 0 1) surface dependent on local configuration
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Titanium-induced charge of Si(0 0 1) surface dependent on local configuration
چکیده انگلیسی
High-resolution X-ray photoemission spectroscopy (XPS) was applied to Ti-deposited Si(0 0 1) surfaces, which were structurally characterized by means of scanning tunneling microscopy (STM). Negative chemical shift of Si due to Ti deposition was assigned to the distorted TiSi bonds formed on the surface. The shift was reduced when a Ti sank beneath a Si dimer. Silicidation resulted in a positive shift to the TiSi bonding. The charge on the Si atoms near Ti was estimated through preliminary natural bonding orbital (NBO) calculation. We show that the shifts can be explained in terms of the sensitivity of charges of Si near Ti to the local structure near the dimer.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electron Spectroscopy and Related Phenomena - Volume 192, January 2014, Pages 35-39
نویسندگان
, , , , , , , , , , ,