کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5396111 | 1505741 | 2013 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Structure of the oxide film on Ti-6Ta alloy after immersion test in 8Â mol/L boiling nitric acid medium
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
By using X-ray photoelectron spectroscopy (XPS), X-ray diffractometer (XRD) and scanning electron microscopy (SEM), we investigate the corrosion behavior and the structure of the oxide film of Ti-6Ta alloy that is subjected to the immersion corrosion test in 8Â mol/L boiling nitric acid for 432Â h. Based on the phase constitution indentified by depth profile XPS, the oxide film could be divided into three sub-layers along its thickness direction: the chemical stable TiO2 and Ta2O5 are present in layer I; the sub-oxide Ti2O3 and TaO are present in the layer II and layer III, and the high valence oxide evolutes from their sub-oxide gradually. Owing to the shielding effect of Ta2O5, the corrosion rate of the Ti-6Ta alloy decreases from 0.051Â mm/y to 0.014Â mm/y with increasing immersion time, showing an excellent corrosion resistance in 8Â mol/L boiling nitric acid.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electron Spectroscopy and Related Phenomena - Volume 189, August 2013, Pages 122-126
Journal: Journal of Electron Spectroscopy and Related Phenomena - Volume 189, August 2013, Pages 122-126
نویسندگان
Dizi Guo, Yingli Yang, Jinping Wu, Bin Zhao, Hengzhang Zhao, Hangbiao Su, Yafeng Lu,