کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5397077 1505775 2007 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effect of plasma treatment on Ni molecular environment in a spent catalyst and a plating sludge
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Effect of plasma treatment on Ni molecular environment in a spent catalyst and a plating sludge
چکیده انگلیسی
All main peaks in the X-ray absorption near-edge structure (XANES) spectra from both plasma-treated wastes and the as-received spent catalyst are characterized with a shoulder towards the edge jump, suggesting a highly distorted Ni(II) environment in all samples except in the as-received plating sludge cake. Results from one-shell fitting of the Fourier transforms of X-ray absorption fine structure (EXAFS) spectra indicate that treating the spent catalyst with plasma barely increases the first-shell coordination number (from 5.59 to 5.81). For the plating sludge cake treated with plasma, however, Ni first-shell coordination number slightly increases from 5.74 to 6.60, suggesting that treatment at >1500 °C with plasma enhances the crystallite size of nickel compounds due to a greater sintering and/or melting reaction. In addition, the Ni second coordination shell in the sludge cake case before plasma treatment is well resolved; while it mixes with the outer (third and greater) shells after plasma treatment. Because the plating sludge cake (i.e., as-received) has never experienced any high-temperature environment like which the spent catalyst did prior to the plasma treatment, it is concluded that plasma treatment incurs considerable change in Ni molecular environment in the plating sludge cake.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electron Spectroscopy and Related Phenomena - Volumes 156–158, May 2007, Pages 232-235
نویسندگان
, , , , ,