کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5397164 1392322 2007 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Morphology and composition of nanoscale surface oxides on Fe-20Cr-18Ni{1 1 1} austenitic stainless steel
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Morphology and composition of nanoscale surface oxides on Fe-20Cr-18Ni{1 1 1} austenitic stainless steel
چکیده انگلیسی
Surface oxidation ranging from initial stages to the onset of passive oxide layer formation have been investigated on Fe-20Cr-18Ni{1 1 1} single crystal surface by X-ray photoelectron spectroscopy (XPS). Surface segregation of the alloying elements and the morphology of the surface oxide nanostructure were characterized quantitatively by inelastic electron background analysis. Our results demonstrate that by increasing the oxidation temperature the relative concentrations of Fe2+ and Fe3+ cations increase due to their enhanced mobility. Higher temperature also improves the mobility of chromium, thus enhancing its segregation to the oxygen-rich surface and thereby reinforcing the passive layer on the alloy. This is in agreement with the results showing the sudden decrease in oxide film thickness at the oxidation temperatures exceeding 600 K. Additionally, a pronounced segregation of metallic nickel is found in the interface between the surface oxide layer and the bulk alloy.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electron Spectroscopy and Related Phenomena - Volume 154, Issue 3, February 2007, Pages 69-78
نویسندگان
, , , , ,