کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5397208 | 1505776 | 2007 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
New electron-ion coincidence setup: Fragmentation of acetonitrile following N 1s core excitation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A new electron-energy-resolved electron-ion coincidence setup was developed based on the Scienta SES-100 hemispherical electron analyzer and a Wiley-McLaren type ion TOF spectrometer. With this setup, an electron-ion coincidence study of gas-phase acetonitrile (CH3CN) was performed using synchrotron radiation. The fragmentation patterns in coincidence with resonant Auger electrons were recorded, following N 1s core excitations to the molecular orbital of the ÏCNâ character. Also the dissociation of doubly charged molecular ions produced after normal Auger decay of N 1sâ1 core-hole states was investigated from PEPICO and PEPIPICO maps. Kinetic energy releases in some reactions were determined with the aid of Monte-Carlo modelling.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electron Spectroscopy and Related Phenomena - Volume 155, Issues 1â3, March 2007, Pages 141-147
Journal: Journal of Electron Spectroscopy and Related Phenomena - Volume 155, Issues 1â3, March 2007, Pages 141-147
نویسندگان
E. Kukk, R. Sankari, M. Huttula, A. Sankari, H. Aksela, S. Aksela,