کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5397811 | 1505873 | 2017 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Influence of the linkage mode and D/A ratio of carbazole/oxadiazole based host materials on phosphorescent organic light-emitting diodes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In the present study, by combining mCP with oxadiazole through tuning the linkage mode and donor/acceptor (D/A) ratio, six different bipolar host materials, o-mCPOXD, m-mCPOXD, p-mCPOXD, oâ2mCPOXD, mâ2mCPOXD, and pâ2mCPOXD were designed and synthesized. Their thermal, photophysical, and electrochemical properties were investigated to reveal the relationship between molecular structure and properties. To evaluate the electroluminescent properties of the six host materials, blue, green, and red phosphorescent organic light-emitting diodes (PhOLEDs) were fabricated and characterized. The compounds with ortho-linkage, o-mCPOXD and oâ2mCPOXD, exhibit the highest triplet energy (ET) value of 2.8Â eV, which is sufficiently high for blue phosphorescent emitters. The PhOLEDs hosted by hybrids with para-linkage, p-mCPOXD and pâ2mCPOXD, show highest current densities but lowest efficiencies due to the relatively low ET value and unbalanced charge flux. The increase of mCP unit leads to lower current densities and device efficiencies. These results demonstrate that bipolar host materials for high-performance PhOLEDs can be constructed by considering the influence of both the linkage mode and D/A ratio.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 188, August 2017, Pages 612-619
Journal: Journal of Luminescence - Volume 188, August 2017, Pages 612-619
نویسندگان
Yali Zhao, Qingxun Guo, Xiaoping Li, Qiang Wang, Dongge Ma,