کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5398041 | 1505880 | 2017 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Luminescence and scintillation properties of Mg-codoped LuAG:Pr single crystals annealed in air
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The influence of the Mg2+ codoping and annealing in the air on the scintillation and luminescence characteristics of Pr-doped lutetium-aluminum garnet crystals (LuAG) was studied to find a possible positive effect of Pr4+. The overall scintillation efficiency under X-ray excitation of the annealed Pr- doped samples decreased with increasing Mg concentration. This was explained by increased overlap of the Pr3+ 5d-4f emission with the charge-transfer (CT) absorption band of the Pr4+ ion stabilized by Mg2+. This absorption caused even greater decrease of the light yield, as the light is collected from the whole sample volume in the pulse-height spectrum measurement. Electron centers based on oxygen vacancies (F+ centers) which can have negative influence on scintillation mechanism were revealed by the electron paramagnetic resonance (EPR) experiments. The O- hole center was detected as well and the temperature dependences of the EPR spectra showed that its thermal stability was decreased by Mg codoping. Negligible changes in the decay time of Pr3+ 5d-4f photoluminescence exclude the non-radiative energy transfer from relaxed 5d1 excited state of Pr3+ towards CT absorption transition of Pr4+ and suggest that simple reabsorption of the emitted light takes place. Unlike for the Ce-doped analogs, promoting the Pr3+ luminescence center to the tetravalent state by divalent ion co-doping and air annealing did not improve scintillation properties of Pr-doped LuAG.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 181, January 2017, Pages 277-285
Journal: Journal of Luminescence - Volume 181, January 2017, Pages 277-285
نویسندگان
Jan Pejchal Jan Pejchal, Maksym Buryi, Vladimir Babin, Petr Prusa, Alena Beitlerova, Jan Barta Jan Barta, Lubomir Havlak, Kei Kamada, Akira Yoshikawa, Valentin Laguta, Martin Nikl,