کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5398429 | 1505883 | 2016 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Optical absorption and fluorescence properties of trivalent lanthanide chlorides in high temperature molten LiCl-KCl eutectic
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The absorption and fluorescence spectroscopic properties of all series of lanthanide elements (La, Ce, â¦, Yb, Lu) were investigated in high temperature molten LiCl-KCl eutectic. Based on absorption spectra, the molar absorptivities for major absorption bands of lanthanides (Ln) were determined by analyzing the calibration curves at various concentrations. Moreover, the nephelauxetic parameters, β, for lanthanides in molten LiCl-KCl salt were evaluated by comparing those for aqueous lanthanide ions. In addition, fluorescence spectra and lifetimes of lanthanide elements were obtained at various Ln(III) concentrations, and this is the first to systematically present fluorescence spectroscopic properties of the whole lanthanide elements in high temperature molten LiCl-KCl salt. Such absorption and fluorescence spectra can provide a fundamental basis for the understanding and development of various pyrochemical processes in molten LiCl-KCl eutectic.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 178, October 2016, Pages 331-339
Journal: Journal of Luminescence - Volume 178, October 2016, Pages 331-339
نویسندگان
Bong Young Kim, Jong-Il Yun,