کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5398889 1505898 2015 39 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Spectroscopic properties of tellurite glasses co-doped with Er3+ and Yb3+
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Spectroscopic properties of tellurite glasses co-doped with Er3+ and Yb3+
چکیده انگلیسی
Spectroscopic characterization of Er3+/Yb3+ co-doped tellurite glasses 70.8TeO2-5Al2O3-13K2O-(11−x)-BaO-0.2Er2O3-xYb2O3, where x=0, 0.4, 0.8, 1.2 and 2 mol% has been carried out through X-ray diffraction, Raman, absorption and luminescence spectra. The Judd-Ofelt intensity parameters were calculated for 0.2 mol% Er3+-doped glass and are used to evaluate radiative properties such as transition probabilities, branching ratios and radiative lifetime. The emission cross-section of the 4I13/2→4I15/2 transition has been calculated from the absorption data using McCumber׳s theory. The emission intensity of both, visible and infrared signals as a function of Yb2O3, have been studied under 980 nm and 375 nm laser excitation. The physical mechanisms responsible for both, visible and infrared signals in the tellurite samples have been explained in terms of the energy transfer and excited state absorption process. The FWHM of the 4I13/2→4I15/2 transition as a function of Yb2O3 mol% and distance (δ) between the laser focusing point and the end-face of the glass has been reported. It was observed both, experimentally and numerically, a change in the FWHM with variations of δ less than 8 mm. The latter was attributed to the radiation trapping effect.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 162, June 2015, Pages 72-80
نویسندگان
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