کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5399050 | 1392673 | 2016 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Up- and down-conversion emissions from Er3+ doped K2YF5 and K2YbF5 crystals
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
Crystals of Er3+ doped K2YF5 and K2YbF5 as well as stoichiometric K2ErF5 have been grown under hydrothermal conditions. Peculiarities of Er3+ luminescence in these crystals have been studied under different excitation wavelengths and, in particular, it has been discovered that in 5Â at% Er3+:K2YbF5, the energy transfer (ET) efficiency from Yb3+ to Er3+ reaches 67%. Under near-IR excitation at 980Â nm, this crystal is characterized by intense yellow up-conversion luminescence with CIE coordinates: x=0.449, y=0.465. Under UV and visible excitation at 355 and 532Â nm, respectively, clear evidences of the down-conversion process through the cross-relaxation have been found. The corresponding efficiency of ET from Er3+ to Yb3+ is 69%. These features make Er3+:K2YbF5 crystals attractive for developing luminescent up- and down-converters for enhancing the performance of solar cells.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 170, Part 1, February 2016, Pages 1-7
Journal: Journal of Luminescence - Volume 170, Part 1, February 2016, Pages 1-7
نویسندگان
P.A. Loiko, N.M. Khaidukov, J. Méndez-Ramos, E.V. Vilejshikova, N.A. Skoptsov, K.V. Yumashev,