کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5399136 | 1392674 | 2016 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and luminescent properties of Eu3+/Eu2+ co-doped calcium aluminosilicate glass-ceramics
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Eu3+ and Eu2+ co-doped calcium aluminosilicate glass-ceramics have been prepared by devitrification of calcium aluminosilicate glass using heat-treatment. Control of crystallization in the glass-ceramics was studied by X-ray diffraction (XRD) and Raman spectroscopy. The results showed that crystalline phases in glass-ceramic belong to the family of melilite Ca2Mg0.25Al1.5Si1.25O7 as the major phase and anorthite CaAl2Si2O8 as the minor phase. Luminescent properties were investigated by emission; lifetime and the color points were calculated. Emission spectra showed that Eu2+ entered into the crystalline phase in a two steps mechanism: first as Eu3+ which is then reduced to Eu2+. This incorporation in the crystal enhanced Eu2+ emission with increasing time of heat-treatment and therefore crystallization.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 169, Part B, January 2016, Pages 528-533
Journal: Journal of Luminescence - Volume 169, Part B, January 2016, Pages 528-533
نویسندگان
H. Bouchouicha, G. Panczer, D. de Ligny, Y. Guyot, M.L. Baesso, L.H.C. Andrade, S.M. Lima, R. Ternane,