کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5399161 | 1392674 | 2016 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Local site symmetry of Sm3+ in sol-gel derived αâ²-Sr2SiO4: Probed by emission and fluorescence lifetime spectroscopy
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Local site symmetry of Sm3+ in sol-gel derived αâ²-Sr2SiO4: Probed by emission and fluorescence lifetime spectroscopy Local site symmetry of Sm3+ in sol-gel derived αâ²-Sr2SiO4: Probed by emission and fluorescence lifetime spectroscopy](/preview/png/5399161.png)
چکیده انگلیسی
Trivalent samarium-doped strontium silicate (Sr2SiO4) phosphors were prepared by sol-gel synthesis using tetra ethyl orthosilicate (TEOS) as precursor. The synthesis temperature could be brought down to 600 °C for the formation of a single phase sample. The emission and excitation spectra, and decay curves were employed to study the luminescence properties. The calcined powders of the Sm3+ ions doped in the Sr2SiO4 emit reddish orange light. In our present study, the 4G5/2â6H5/2 (MD) transition of Sm3+ ions is less intense than 4G5/2â6H9/2 (ED) transition. This indicates that Sm3+ ions preferentially occupy asymmetric site in α-Sr2SiO4. Fluorescence life time measurement has shown monoexponential behavior for Sm3+ in strontium silicate with lifetime value of 2.23 ms. Based on lifetime and emission spectra, it can be inferred that Sm3+ occupies 9-coordinated Sr2+ site in strontium silicate. Based on stark splitting pattern it was inferred that site symmetry around Sm3+ is C3v which further justifies it׳s occupancy in 9-coordinated sites. It was observed that, the emission intensity of Sm3+ increases with the increase in concentration initially, reaching maxima at 1.0 mol % and then decreases with the increasing concentration due to concentration quenching. At higher concentrations (x>0.01), however, the observed decay curves were bi-exponential.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 169, Part B, January 2016, Pages 669-673
Journal: Journal of Luminescence - Volume 169, Part B, January 2016, Pages 669-673
نویسندگان
Santosh K. Gupta, N. Pathak, S.K. Thulasidas, V. Natarajan,