کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5399169 | 1392674 | 2016 | 15 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
New strategies invonving upconverting nanoparticles for determining moderate temperatures by luminescence thermometry
ترجمه فارسی عنوان
استراتژی های جدید در جهت تبدیل نانوذرات به منظور تعیین درجه حرارت متوسط با استفاده از ترمومتری لومینسانس
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
چکیده انگلیسی
Here we analyze alternative luminescence thermometry techniques to FIR, such as intensity ratio luminescence thermometry between the emission arising from two electronic levels that are not necessarily thermally coupled, but that show different evolutions with temperature, and lifetime luminescence nanothermometry in (Ho,Tm,Yb):KLu(WO4)2 and (Er,Yb):NaY2F5O nanoparticles. (Ho,Tm,Yb):KLu(WO4)2 nanoparticles exhibited a maximum relative sensitivity of 0.61%Â Kâ1, similar to that achievable in Er-doped systems, which are the upconverting systems presenting the highest sensitivity. From another side, (Er,Yb):NaY2F5O nanocrystals show great potentiality as thermal sensors at the nanoscale for moderate temperatures due to the incorporation of additional non-radiative relaxation mechanisms that shorten the emission lifetime generated by the oxygen present in the structure when compared to (Er,Yb):NaYF4 nanoparticles exhibiting the highest upconversion efficiency. We used those nanoparticles for ex-vivo temperature determination by laser induced heating in chicken breast using lifetime-based thermometry. The results obtained indicate that these techniques might constitute alternatives to FIR with potential applications for the determination of moderate temperatures, with sensitivities comparable to those that can be achieved by FIR or even higher.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 169, Part B, January 2016, Pages 711-716
Journal: Journal of Luminescence - Volume 169, Part B, January 2016, Pages 711-716
نویسندگان
Ol.A. Savchuk, J.J. Carvajal, M.C. Pujol, J. Massons, P. Haro-González, O. MartÃnez, J. Jiménez, M. Aguiló, F. DÃaz,