کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5399422 1505905 2014 23 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A comparison of the transition metal 3d1 crystal field splitting with the lanthanide 5d1 crystal field splitting in compounds
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
A comparison of the transition metal 3d1 crystal field splitting with the lanthanide 5d1 crystal field splitting in compounds
چکیده انگلیسی
Spectroscopic data on the 3d1 transition metal activators Ti3+, V4+ and Cr5+ in compounds were collected and analysed in order to obtain an overview on the size of the 3d1 level crystal field splitting. Results are compared with data on the 5d1 activators Ce3+ and Eu2+. Trends earlier observed for the 5d1 lanthanides also apply to the 3d1 transition metals. They will be interpreted with the point charge electrostatic model and a modified version thereof.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 155, November 2014, Pages 135-140
نویسندگان
, ,