کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5399441 | 1505905 | 2014 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Enhancing photoluminescence with Li-doped CaTiO3:Eu3+ red phosphors prepared by solid state synthesis
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Red phosphors of Li-doped CaTiO3:Eu3+ that enhance photoluminescence have been synthesized by a solid-state method, and their structure and morphology were confirmed by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The luminescence property was measured using photoluminescence excitation (PLE) and photoluminescence (PL) spectra, respectively. The effect of sintered temperature and Eu3+ and Li+ concentration in as-prepared series phosphors was studied. Results indicate that the optimal luminescence properties of CaTiO3:Eu3+ (CTE) phosphors are typically obtained at 1300 °C with 12 mol% of Eu3+ concentration, and the emission intensity can be greatly enhanced by the incorporation of Li+ into the CTE phosphors, attributing that Li not only compensates positive charge defect by replacement of Ca2+ with Eu3+, but also plays a role of flux, which could enhance the crystallinity of the phosphors. The intensity of the optimal Li-doped CaTiO3:Eu3+ phosphor (CLTE) is 2.3 times of that of CTE. PL spectrum showed that CLTE phosphor was efficiently excited by near-ultraviolet light at wavelength around 398 nm and emitted intensive red light with a peak around 616 nm corresponding to the 5D0â7F2 transition of Eu3+. Furthermore, this phosphor has very good thermal stability and high color purity, implying the potential to be a promising red phosphor in white light emitting diodes.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 155, November 2014, Pages 269-274
Journal: Journal of Luminescence - Volume 155, November 2014, Pages 269-274
نویسندگان
Yibing Wu, Zhuo Sun, Kaibin Ruan, Yong Xu, Hong Zhang,